MICHELA SALAMONE

Professore associato

email: michela.salamone@uniroma2.it
telefono: 06 72594387
edificio: Sogene settore G livello 1
stanza: 10

Michela Salamone si è laureata nel 1999 con lode in Chimica (Università degli Studi di Roma “La Sapienza”) e nel 2003 ha conseguito il Dottorato in Scienze Chimiche (Università degli Studi di Roma “Tor Vergata”, XV ciclo) sotto la supervisione del Prof. Massimo Bietti. Negli anni 2003-2007 è stata assegnista di Ricerca presso il Dipartimento di Scienze e Tecnologie Chimiche dell’Università degli Studi di Roma “Tor Vergata”. Ha svolto attività di ricerca all'estero presso il Max Planck Institut für Strahlenchemie, Mülheim an der Ruhr (Germania) e nell’ambito dell'European Commission's Transnational Access to Major Research Infrastructures presso il Daresbury Laboratory ed il Rutherford Appleton Laboratory (UK). Nel Novembre 2007 ha preso servizio come Ricercatore Universitario. Nel Marzo 2017 ha conseguito l'abilitazione a Professore Associato (ASN, II fascia) per il Settore Concorsuale 03/C1-Chimica Organica e da Aprile 2019 è in servizio come Professore Associato presso il Dipartimento di Scienze e Tecnologie Chimiche dell’Università degli Studi di Roma “Tor Vergata”, SSD: CHIM/06 CHIMICA ORGANICA. Attualmente insegna i corsi di Chimica Organica per il Corso di Laurea Triennale in Scienze Biologiche, il corso di Laboratorio di Chimica Organica per i Corsi di Laurea in Chimica e Chimica Applicata. La sua attività scientifica riguarda lo studio cinetico di reazioni uni- e bimolecolari (frammentazioni, trasposizioni e reazioni di trasferimento di atomo) di intermedi reattivi quali alcossi e amminossi radicali mediante l’impiego di tecniche risolte nel tempo quali la laser flash fotolisi e l'applicazione di queste informazioni meccanicistiche allo sviluppo di procedure sinteticamente utili. I risultati di questi studi hanno portato alla pubblicazione di 72 lavori su riviste internazionali.

Produzione scientifica

2108/346327 - 2023 - Highly Selective C(sp3)–H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhancement
Sisti, Sergio; Galeotti, Marco; Scarchilli, Filippo; Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (Washington, DC : American Chemical Society, 1879-) pp. 22086-22096 - issn: 1520-5126 - wos: WOS:001072658500001 (6) - scopus: 2-s2.0-85173588208 (6)

2108/346325 - 2023 - Activation and Deactivation of Benzylic C−H Bonds Guided by Stereoelectronic Effects in Hydrogen Atom Transfer from Amides and Amines to Alkoxyl Radicals
Sisti, Sergio; Ioele, Fabio; Scarchilli, Filippo; Galeotti, Marco; Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (Weinheim : Wiley-VCH-Verl.) pp. - - issn: 1099-0690 - wos: WOS:001083986000001 (0) - scopus: 2-s2.0-85168904267 (0)

2108/346326 - 2023 - Radical and Cationic Pathways in C(sp3)–H Bond Oxygenation by Dioxiranes of Bicyclic and Spirocyclic Hydrocarbons Bearing Cyclopropane Moieties
Galeotti, Marco; Sisti, Sergio; Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (Washington, DC : American Chemical Society, 1879-) pp. 24021-24034 - issn: 1520-5126 - wos: WOS:001092755100001 (1) - scopus: 2-s2.0-85176495201 (1)

2108/315397 - 2023 - Antioxidant activities of hydroxylated naphthalenes: the role of aryloxyl radicals
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: CHEMPLUSCHEM (Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) pp. - - issn: 2192-6506 - wos: WOS:000918293600001 (2) - scopus: 2-s2.0-85147038263 (2)

2108/313588 - 2022 - Resolving oxygenation pathways in manganese-catalyzed C(sp3)-H functionalization via radical and cationic intermediates
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (Washington, DC : American Chemical Society, 1879-) pp. 7391-7401 - issn: 1520-5126 - wos: WOS:000799141600042 (20) - scopus: 2-s2.0-85128627222 (21)

2108/313586 - 2022 - Factors governing reactivity and selectivity in hydrogen atom transfer from C(sp3)-H bonds of nitrogen-containing heterocycles to the cumyloxyl radical
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY (Washington, DC : American Chemical Society, 1936-) pp. 7456-7463 - issn: 1520-6904 - wos: WOS:000809765000040 (8) - scopus: 2-s2.0-85131769194 (8)

2108/313585 - 2022 - Electronic control over site-selectivity in hydrogen atom transfer (HAT) based C(sp3)-H functionalization promoted by electrophilic reagents
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: CHEMICAL SOCIETY REVIEWS (London: Royal Society of Chemistry) pp. 2171-2223 - issn: 1460-4744 - wos: WOS:000762415600001 (85) - scopus: 2-s2.0-85127730129 (87)

2108/280327 - 2021 - Practical and selective sp3 C-H bond chlorination via aminium radicals
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION (Wiley-VCH Verlag GmBH:PO Box 101161, D 69451 Weinheim Germany:011 49 6201 606147, EMAIL: service@wiley-vch.de, INTERNET: http://www.wiley-vch.de, Fax: 011 49 6201 606328) pp. 7132-7139 - issn: 1433-7851 - wos: WOS:000621371500001 (32) - scopus: 2-s2.0-85101617072 (34)

2108/280371 - 2021 - Deciphering reactivity and selectivity patterns in aliphatic C−H bond oxygenation of cyclopentane and cyclohexane derivatives
Martin, Teo; Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 9925-9937 - issn: 0022-3263 - wos: WOS:000684025500001 (7) - scopus: 2-s2.0-85108640033 (7)

2108/280377 - 2021 - Bimodal Evans−Polanyi relationships in hydrogen atom transfer from C(sp3)−H bonds to the cumyloxyl radical. A combined time-resolved kinetic and computational study
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY ([Washington, USA: American Chemical Society] 1879-) pp. 11759-11776 - issn: 0002-7863 - wos: WOS:000684586600048 (49) - scopus: 2-s2.0-85112697325 (49)

2108/232202 - 2019 - Hydrogen Atom Transfer from 1,2- and 1,3-Diols to the Cumyloxyl Radical. The Role of Structural Effects on Metal-Ion Induced C-H Bond Deactivation
Martin, Teo; Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: CHEMICAL COMMUNICATIONS ([London] : Royal Society of Chemistry) pp. 5227-5230 - issn: 1364-548X - wos: WOS:000468342700003 (3) - scopus: 2-s2.0-85065080450 (3)

2108/215915 - 2019 - Evaluation of Polar Effects in Hydrogen Atom Transfer Reactions from Activated Phenols
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY (Washington, DC : American Chemical Society, 1936-) pp. 1778-1786 - issn: 1520-6904 - wos: WOS:000459367100010 (16) - scopus: 2-s2.0-85061272476 (17)

2108/201048 - 2018 - Characterization and Fate of Hydrogen-Bonded Free-Radical Intermediates and Their Coupling Products from the Hydrogen Atom Transfer Agent 1,8-Naphthalenediol
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: ACS OMEGA (Washington, D.C. : American Chemical Society, 2016-) pp. 3918-3927 - issn: 2470-1343 - wos: WOS:000430200300033 (29) - scopus: 2-s2.0-85045114164 (29)

2108/201050 - 2018 - Hydrogen Atom Transfer from Alkanols and Alkanediols to the Cumyloxyl Radical. A Kinetic Evaluation of the Contribution of α-C-H Activation and β-C-H Deactivation
Salamone, Michela; Martin, Teo; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5539-5545 - issn: 0022-3263 - wos: WOS:000432900800020 (10) - scopus: 2-s2.0-85046452623 (11)

2108/201046 - 2018 - Enhancing Reactivity and Site-Selectivity in Hydrogen Atom Transfer from Amino Acid C-H Bonds via Deprotonation
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 808-811 - issn: 1523-7060 - wos: WOS:000424729800079 (9) - scopus: 2-s2.0-85041580644 (9)

2108/210580 - 2018 - The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C-H Bond Oxygenation
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ACCOUNTS OF CHEMICAL RESEARCH (Washington, DC : American Chemical Society, 1968-) pp. 1984-1995 - issn: 1520-4898 - wos: WOS:000445441200011 (117) - scopus: 2-s2.0-85053558274 (124)

2108/201044 - 2017 - Electronic and Torsional Effects on Hydrogen Atom Transfer from Aliphatic C-H Bonds: A Kinetic Evaluation via Reaction with the Cumyloxyl Radical
Salamone, Michela; Martin, Teo; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 13542-13549 - issn: 0022-3263 - wos: WOS:000418392600057 (11) - scopus: 2-s2.0-85038439573 (11)

2108/201042 - 2017 - Tuning Selectivity in Aliphatic C−H Bond Oxidation of N-Alkylamides and Phthalimides Catalyzed by Manganese Complexes
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ACS CATALYSIS (Washington, DC : American Chemical Society, c2011-) pp. 5903-5911 - issn: 2155-5435 - wos: WOS:000410005700038 (45) - scopus: 2-s2.0-85029049745 (49)

2108/201040 - 2017 - Aerobic Oxidation of 4-Alkyl-N,N-dimethylbenzylamines Catalyzed by N-Hydroxyphtalimide: Protonation-Driven Control over Regioselectivity
Bietti, Massimo; Martin, Teo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5761-5768 - issn: 0022-3263 - wos: WOS:000402851000025 (15) - scopus: 2-s2.0-85019985221 (16)

2108/201032 - 2016 - Fine Control over Site and Substrate Selectivity in Hydrogen Atom Transfer Based Functionalization of Aliphatic C-H Bonds
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 9269-9278 - issn: 0022-3263 - wos: WOS:000385054300056 (19) - scopus: 2-s2.0-84990848556 (20)

2108/201038 - 2016 - Kinetic Study of the Reaction of the Phthalimide-N-Oxyl Radical with Amides: Structural and Medium Effects on the Hydrogen Atom Transfer Reactivity and Selectivity
Bietti, Massimo; Martin, Teo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 11924-11931 - issn: 0022-3263 - wos: WOS:000389396400040 (18) - scopus: 2-s2.0-85000979478 (19)

2108/172201 - 2016 - Oxidation of Aryl Diphenylmethyl Sulfides Promoted by a Nonheme Iron(IV)-Oxo Complex: Evidence for an Electron Transfer-Oxygen Transfer Mechanism
Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 2513-2520 - issn: 0022-3263 - wos: WOS:000372664700030 (21) - scopus: 2-s2.0-84961779057 (21)

2108/172203 - 2016 - Hydrogen atom transfer from tertiary alkanamides to the cumyloxyl radical. The role of substrate structure on alkali and alkaline earth metal ion induced C–H bond deactivation
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: TETRAHEDRON (Elsevier Science Limited:Oxford Fulfillment Center, PO Box 800, Kidlington Oxford OX5 1DX United Kingdom:011 44 1865 843000, 011 44 1865 843699, EMAIL: asianfo@elsevier.com, tcb@elsevier.co.UK, INTERNET: http://www.elsevier.com, http://www.elsevier.com/locate/shpsa/, Fax: 011 44 1865 843010) pp. 7757-7763 - issn: 0040-4020 - wos: WOS:000388781600014 (5) - scopus: 2-s2.0-84973551333 (6)

2108/172197 - 2016 - Competitive Hydrogen Atom Transfer to Oxyl- and Peroxyl Radicals in the Cu-Catalyzed Oxidative Coupling of N-Aryl Tetrahydroisoquinolines Using tert-Butyl Hydroperoxide
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ACS CATALYSIS (Washington, DC : American Chemical Society, c2011-) pp. 3253-3261 - issn: 2155-5435 - wos: WOS:000375894500063 (52) - scopus: 2-s2.0-84973532641 (53)

2108/172199 - 2016 - A computational and experimental re-examination of the reaction of the benzyloxyl radical with DMSO
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: COMPUTATIONAL AND THEORETICAL CHEMISTRY (Amsterdam [u.a.] : Elsevier) pp. 74-79 - issn: 2210-271X - wos: WOS:000370305400011 (5) - scopus: 2-s2.0-84958610138 (5)

2108/172187 - 2015 - Binding to Redox-Inactive Alkali and Alkaline Earth Metal Ions Strongly Deactivates the C-H Bonds of Tertiary Amides toward Hydrogen Atom Transfer to Reactive Oxygen Centered Radicals
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 9214-9223 - issn: 0022-3263 - wos: WOS:000361866700031 (16) - scopus: 2-s2.0-84941930746 (17)

2108/172193 - 2015 - Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C-H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ACCOUNTS OF CHEMICAL RESEARCH (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 2895-2903 - issn: 0001-4842 - wos: WOS:000365150500011 (182) - scopus: 2-s2.0-84947236214 (188)

2108/113329 - 2015 - Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release. Equatorial C-H Activation vs Axial C-H Deactivation
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 4710-4715 - issn: 0022-3263 - wos: WOS:000354004600049 (31) - scopus: 2-s2.0-84928902572 (31)

2108/113327 - 2015 - Reactivity and Selectivity Patterns in Hydrogen Atom Transfer from Amino Acid C-H Bonds to the Cumyloxyl Radical. Polar Effects as a Rationale for the Preferential Reaction at Proline Residues
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 3643-3650 - issn: 0022-3263 - wos: WOS:000352463100028 (26) - scopus: 2-s2.0-84926614614 (26)

2108/113318 - 2014 - Reactions of the Cumyloxyl Radical with Secondary Amides. The Influence of Steric and Stereoelectronic Effects on the Hydrogen Atom Transfer Reactivity and Selectivity
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 6444-6447 - issn: 1523-7060 - wos: WOS:000346759900046 (12) - scopus: 2-s2.0-84919646789 (12)

2108/113315 - 2014 - Absolute Rate Constants for Hydrogen Atom Transfer from Tertiary Amides to the Cumyloxyl Radical. Evaluating the Role of Stereoelectronic Effects
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 7179-7184 - issn: 0022-3263 - wos: WOS:000339983300041 (27) - scopus: 2-s2.0-84905378492 (27)

2108/113305 - 2014 - Importance of pi-Stacking Interactions in the Hydrogen Atom Transfer Reactions from Activated Phenols to Short-Lived N-oxyl Radicals
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5209-5218 - issn: 0022-3263 - wos: WOS:000337073900043 (31) - scopus: 2-s2.0-84902096271 (31)

2108/113323 - 2014 - Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control Over the Hydrogen Atom Transfer Reactivity and Selectivity Through Solvent Polarity and Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 1149-1154 - issn: 0022-3263 - wos: WOS:000348331700047 (20) - scopus: 2-s2.0-84921326735 (21)

2108/113311 - 2014 - Structural and Medium Effects on the Reactions of the Cumyloxyl Radical with Intramolecular Hydrogen Bonded Phenols. The Interplay Between Hydrogen-Bonding and Acid-Base Interactions on the Hydrogen Atom Transfer Reactivity and Selectivity
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 6196-6205 - issn: 0022-3263 - wos: WOS:000338693300029 (15) - scopus: 2-s2.0-84903706667 (16)

2108/113307 - 2014 - Reaction Pathways of Alkoxyl Radicals. The Role of Solvent Effects on C-C Bond Fragmentation and Hydrogen Atom Transfer Reactions
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: SYNLETT (New York ; Stuttgart : Thieme Georg Thieme Verlag Stuttgart:Postfach 301120, D-70451 Stuttgart Germany:011 49 711 8931321, EMAIL: aboservice@thieme.de, INTERNET: http://www.thieme.de, Fax: 011 49 711 8931422) pp. 1803-1816 - issn: 0936-5214 - wos: WOS:000340591900003 (77) - scopus: 2-s2.0-84905588011 (77)

2108/113309 - 2014 - Hydrogen Atom Transfer from 1,n-Alkanediamines to the Cumyloxyl Radical. Modulating C-H Deactivation Through Acid-Base Interactions and Solvent Effects
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5710-5716 - issn: 0022-3263 - wos: WOS:000337871100032 (11) - scopus: 2-s2.0-84903151693 (12)

2108/76315 - 2013 - Tuning Hydrogen Atom Abstraction from the Aliphatic C-H Bonds of Basic Substrates by Protonation. Control Over Selectivity by C-H Deactivation
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: CHEMICAL SCIENCE (Cambridge : Royal Society of Chemistry, 2010-) pp. 3255-3262 - issn: 2041-6520 - wos: WOS:000321307000036 (24) - scopus: 2-s2.0-84880025101 (26)

2108/76307 - 2013 - Reactions of the Phthalimide N-Oxyl Radical (PINO) with Activated Phenols: The Contribution of π-Stacking Interactions to Hydrogen Atom Transfer Rates
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 1026-1037 - issn: 0022-3263 - wos: WOS:000314558300021 (28) - scopus: 2-s2.0-84873392905 (28)

2108/76316 - 2013 - Reactions of the Cumyloxyl and Benzyloxyl Radicals with Tertiary Amides. Hydrogen Abstraction Selectivity and the Role of Specific Substrate-Radical Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5909-5917 - issn: 0022-3263 - wos: WOS:000320979500010 (35) - scopus: 2-s2.0-84879385355 (35)

2108/76314 - 2013 - Modeling Non-Covalent Radical-Molecule Interactions Using Conventional Density-Functional Theory: Beware Erroneous Charge Transfer
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 947-952 - issn: 1089-5639 - wos: WOS:000314908200016 (40) - scopus: 2-s2.0-84873426197 (40)

2108/76291 - 2012 - Effect of Metal Ions on the Reactions of the Cumyloxyl Radical with Hydrogen Atom Donors. Fine Control on Hydrogen Abstraction Reactivity Determined by Lewis Acid-Base Interactions
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY ([Washington, USA: American Chemical Society] 1879-) pp. 415-423 - issn: 0002-7863 - wos: WOS:000313143000064 (28) - scopus: 2-s2.0-84872110820 (30)

2108/76312 - 2012 - Hydrogen Abstraction from Cyclic Amines by the Cumyloxyl and Benzyloxyl Radicals. The Role of Stereoelectronic Effects and of Substrate/Radical Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 8556-8561 - issn: 0022-3263 - wos: WOS:000313767800019 (31) - scopus: 2-s2.0-84867386015 (32)

2108/76309 - 2012 - Reactions of the Cumyloxyl and Benzyloxyl Radicals with Strong Hydrogen Bond Acceptors. Large Enhancements in Hydrogen Abstraction Reactivity Determined by Substrate/Radical Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 10479-10487 - issn: 0022-3263 - wos: WOS:000311926100002 (29) - scopus: 2-s2.0-84870925595 (29)

2108/76317 - 2012 - Kinetic Solvent Effects on Hydrogen Abstraction from Phenol by the Cumyloxyl Radical. Towards an Understanding of the Role of Protic Solvents
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 1267-1272 - issn: 0022-3263 - wos: WOS:000300462700006 (20) - scopus: 2-s2.0-84856673904 (19)

2108/76310 - 2011 - Understanding Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 6110-6113 - issn: 1523-7060 - wos: WOS:000296756600045 (29) - scopus: 2-s2.0-80955133335 (29)

2108/13188 - 2011 - Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical. The Importance of Solvent Hydrogen Bond Interactions with the Substrate and the Abstracting Radical
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 4645-4651 - issn: 0022-3263 - wos: WOS:000291128300032 (30) - scopus: 2-s2.0-79957824992 (32)

2108/13187 - 2011 - One-Electron Oxidation of Ferrocenes by Short-Lived N-oxyl Radicals. The Role of Structural Effects on the Intrinsic Electron Transfer Reactivities
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: ORGANIC & BIOMOLECULAR CHEMISTRY (Royal Society of Chemistry:Thomas Graham House, Science Park, Cambridge CB4 0WF United Kingdom:011 44 1223 432360, EMAIL: sales@rsc.org, INTERNET: http://www.rsc.org, http://www.chensoc.org, Fax: 011 44 1223 423429) pp. 4085-4090 - issn: 1477-0520 - wos: WOS:000290735300016 (17) - scopus: 2-s2.0-79956277793 (17)

2108/76311 - 2011 - Hydrogen Atom Abstraction Reactions from Tertiary Amines by Benzyloxyl and Cumyloxyl Radicals: Influence of Structure on the Rate-Determining Formation of a Hydrogen Bonded Pre-reaction Complex
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 6264-6270 - issn: 0022-3263 - wos: WOS:000293252600041 (25) - scopus: 2-s2.0-79961046338 (26)

2108/76289 - 2011 - Hydrogen Atom Abstraction Selectivity in the Reactions of Alkylamines with the Benzyloxyl and Cumyloxyl Radicals. The Importance of Structure and of Substrate-Radical Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY ([Washington, USA: American Chemical Society] 1879-) pp. 16625-16634 - issn: 0002-7863 - wos: WOS:000295997500054 (45) - scopus: 2-s2.0-80054724967 (47)

2108/13180 - 2011 - Time-Resolved Kinetic Study of the Electron Transfer Reactions Between Ring-Substituted Cumyloxyl Radicals and Alkyl Ferrocenes. Evidence for an Inner-Sphere Mechanism
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 1789-1794 - issn: 0022-3263 - wos: WOS:000288142800031 (9) - scopus: 2-s2.0-79953873112 (9)

2108/13172 - 2010 - The O-neophyl rearrangement of 1,1-diarylalkoxyl radicals. Experimental evidence for the formation of an intermediate 1-oxaspiro[2,5]octadienyl radical
Bietti, Massimo; Cicero, Daniel Oscar; Salamone, Michela - 01 - Articolo su rivista
rivista: TETRAHEDRON LETTERS (Oxford; New York; Paris; Frankfurt: Pergamon Press, 1959-) pp. 4129-4131 - issn: 0040-4039 - wos: WOS:000280053600035 (13) - scopus: 2-s2.0-77953959305 (14)

2108/13171 - 2010 - The Role of Structural Effects on the Reactions of Alkoxyl Radicals with Trialkyl and Triaryl Phosphites. A Time-Resolved Kinetic Study
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 4514-4520 - issn: 0022-3263 - wos: WOS:000279030900020 (21) - scopus: 2-s2.0-77954135916 (21)

2108/13178 - 2010 - Diffusion Controlled Hydrogen Atom Abstraction from Tertiary Amines by the Benzyloxyl Radical. The Importance of C-H/N Hydrogen Bonding
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 260-263 - issn: 1523-7060 - wos: WOS:000286130000023 (20) - scopus: 2-s2.0-78651491501 (22)

2108/13175 - 2010 - Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical. The Role of Hydrogen Bonding
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 3654-3657 - issn: 1523-7060 - wos: WOS:000280799100023 (44) - scopus: 2-s2.0-77955682930 (45)

2108/13176 - 2010 - The Electron Transfer Properties of Alkoxyl Radicals. A Time-Resolved Kinetic Study of the Reactions of the tert-Butoxyl, Cumyloxyl and Benzyloxyl Radicals with Alkyl Ferrocenes
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5875-5881 - issn: 0022-3263 - wos: WOS:000281180100010 (17) - scopus: 2-s2.0-77956147516 (18)

2108/31471 - 2009 - Phenyl Bridging in Ring-Substituted Cumyloxyl Radicals. A Product and Time-Resolved Kinetic Study
Salamone, Michela; Bietti, Massimo - 01 - Articolo su rivista
rivista: ORGANIC LETTERS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 2453-2456 - issn: 1523-7060 - wos: WOS:000266546300058 (21) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-66149160251&partnerID=40&md5=a598867d4be504ca39f800ed28ab0aaf (0)

2108/35258 - 2007 - DFT evidence for a stepwise mechanism in the O-neophyl rearrangement of 1,1-diarylalkoxyl radicals
Bietti, Massimo; Ercolani, Gianfranco; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 4515-4519 - issn: 0022-3263 - wos: WOS:000246893400029 (17) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-34250222040&partnerID=40&md5=ee99d1cbeb943672f4bf9f4f117bb4ff (0)

2108/39128 - 2006 - Involvement of alkoxyl radical intermediates in the photolysis of 1-alkylcycloalkanols in the presence of bis(pyridine) iodonium tetrafluoroborate - Comparison with the (diacetoxyiodo)benzene/I-2 system
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY. A, CHEMISTRY (Lausanne : Elsevier Sequoia) pp. 33-37 - issn: 1010-6030 - wos: WOS:000239712300005 (1) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-33745984838&partnerID=40&md5=cc29c6a010af2f9c5b7d905f79716692 (0)

2108/39214 - 2006 - Oxygen acidity of ring methoxylated 1,1-diarylalkanol radical cations bearing alpha-cyclopropyl groups. The competition between O-neophyl shift and C-cyclopropyl beta-scission in the intermediate 1,1-diarylalkoxyl radicals
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 3167-3175 - issn: 0022-3263 - wos: WOS:000236678100031 (5) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-33645784524&partnerID=40&md5=d891a6a9e1e1339acfe667be589b0a7a (0)

2108/38245 - 2005 - The effect of ring substitution on the O-neophyl rearrangement of 1,1-diarylalkoxyl radicals. A product and time-resolved kinetic study
Bietti, Massimo; Ercolani, Gianfranco; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 3884-3891 - issn: 0022-3263 - wos: WOS:000228983300016 (61) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-18744377711&partnerID=40&md5=f42babf0ca62e9db9adbd5b8e8b39e87 (0)

2108/38263 - 2005 - Structural effects on the beta-scission reaction of alkoxyl radicals. Direct measurement of the absolute rate constants for ring opening of benzocycloalken-1-oxyl radicals
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 1417-1422 - issn: 0022-3263 - wos: WOS:000227075600037 (27) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-13844314452&partnerID=40&md5=d74547499a76817b84be0f2e3c7c1895 (0)

2108/38252 - 2005 - Structural effects on the beta-scission reaction of tertiary arylcarbinyloxyl radicals. The role of alpha-cyclopropyl and alpha-cyclobutyl groups
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 6820-6826 - issn: 0022-3263 - wos: WOS:000231183000031 (25) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-23644452967&partnerID=40&md5=3c2ef942576722f95c9b4dc0add821b1 (0)

2108/38273 - 2005 - Solvent effects on the o-neophyl rearrangement of 1,1-diarylalkoxyl radicals. A laser flash photolysis study
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 10603-10606 - issn: 0022-3263 - wos: WOS:000233761500054 (22) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-28744431950&partnerID=40&md5=be59dd019e0b3fa86feaa96ac651b3c3 (0)

2108/33057 - 2004 - Photolysis of 1-alkylcycloalkanols in the presence of (diacetoxyiodo)benzene and I-2. Intramolecular selectivity in the beta-scission reactions of the intermediate 1-alkylcycloalkoxyl radicals
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF ORGANIC CHEMISTRY ([Washington, D.C: American Chemical Society) pp. 5281-5289 - issn: 0022-3263 - wos: WOS:000223008100015 (29) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-3543007143&partnerID=40&md5=b1ee119ed8178810803447eed78468fd (0)

2108/33087 - 2004 - Early stages in the TiO2-photocatalyzed degradation of simple phenolic and non-phenolic lignin model compounds
Bietti, Massimo; Salamone, Michela - 01 - Articolo su rivista
rivista: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY. A, CHEMISTRY (Lausanne : Elsevier Sequoia) pp. 453-462 - issn: 1010-6030 - wos: WOS:000221685700022 (42) - scopus: http://www.scopus.com/inward/record.url?eid=2-s2.0-2342620706&partnerID=40&md5=bd3c5774d58bff321ec42b7d6993b680 (0)

2108/201019 - 2003 - Kinetic Evidence of an Arm-Off Mechanism in Complexes of Hemilabile Hybrid Ligands. Oxidative Addition of Methyl Iodide to the Rhodium(I) Complex [Rh(2,6-bis(benzylthiomethyl)pyridine)(CO)]PF6 via Competitive Pathways
Salamone, Michela - 01 - Articolo su rivista
rivista: ORGANOMETALLICS (American Chemical Society:1155 Sixteenth Street Northwest:Washington, DC 20036:(800)227-5558, EMAIL: service@acs.org, INTERNET: http://www.pubs.acs.org, Fax: (614)447-3671) pp. 247-252 - issn: 0276-7333 - wos: WOS:000188083900015 (28) - scopus: 2-s2.0-0742321793 (29)

2108/201254 - 2002 - The role of stereoelectronic effects on the side-chain fragmentation of alkylaromatic radical cations. The reactivity of 5-methoxy-2,2-dimethylindan-1-ol radical cation
Bietti, Massimo; Ercolani, Gianfranco; Salamone, Michela - 01 - Articolo su rivista
rivista: TETRAHEDRON (Elsevier Science Limited:Oxford Fulfillment Center, PO Box 800, Kidlington Oxford OX5 1DX United Kingdom:011 44 1865 843000, 011 44 1865 843699, EMAIL: asianfo@elsevier.com, tcb@elsevier.co.UK, INTERNET: http://www.elsevier.com, http://www.elsevier.com/locate/shpsa/, Fax: 011 44 1865 843010) pp. 5039-5044 - issn: 0040-4020 - wos: WOS:000176320500003 (6) - scopus: 2-s2.0-0037124524 (6)

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